کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1328538 | 977589 | 2006 | 11 صفحه PDF | دانلود رایگان |
The implications of the Complementary Spherical Electron Density Model, originally developed by Mingos and Hawes in 1985 and amplified in 2004, to co-ordinatively unsaturated intermediates in homogenous catalytic processes are discussed. The geometric consequences of the model for 16 and 14 electron complexes are particularly important and are supported by numerous recent X-ray crystallographic investigations. The character of the important frontier orbitals have been explored using density functional calculations.
The implications of the Complementary Spherical Electron Density Model to co-ordinatively unsaturated intermediates in homogenous catalytic processes are discussed. The geometric consequences of the model for 16 and 14 electron complexes are particularly important and are supported by numerous recent X-ray crystallographic investigations.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 14, 1 July 2006, Pages 3165–3175