کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1328581 | 977599 | 2006 | 7 صفحه PDF | دانلود رایگان |
This paper reports the results obtained in a study on the radical hydrostannation of mono- and disubstituted alkynes with bulky triorganotin hydrides using triethylborane as initiator. The addition of trineophyl- (1), tris[(phenyldimethylsilyl)methyl]- (2), and 9-tripticyldimethyltin (3) hydride to eight alkynes was carried out at room temperature leading to vinylstannanes in good to excellent yields and, mostly, with complete stereoselectivity. The results obtained in a study on the relative reactivity of trineophyl- (1), tris[(phenyldimethylsilyl)methyl]- (2), 9-triptycyldimethyltin (3) hydrides, and tri-n-butyltin hydride (29) using the radical reactions between these hydrides and 6-bromo-1-hexene (28) are also reported. Full 1H-, 13C-, and 119Sn NMR characteristics are included.
The hydrostannation at room temperature initiated by triethylborane of eight alkynes with trineophyl- (1), tris[(phenyldimethylsilyl)methyl]- (2), and 9-triptycyldimethyltin (3) hydrides leads to vinylstannanes in good to excellent yields and with, mostly, complete stereoselectivity. The relative reactivity of 1–3 and tri-n-butyltin hydride could be deduced from their radical reactions with 6-bromo-1-hexene.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 6, 1 March 2006, Pages 1085–1091