کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1328582 | 977599 | 2006 | 9 صفحه PDF | دانلود رایگان |
Two new mononuclear mercury(II) alkynyl complexes containing substituted bithiazole unit [R–CC–HgMe] (2) and [R–CC–Hg–CC–R] (3) (R = 4,4′-di(tert-butyl)-2,2′-bithiazol-5-yl) were prepared in good yields by mercuration of 4,4′-di(tert-butyl)-5-ethynyl-2,2′-bithiazole (1) at room temperature via the dehydrohalogenation reaction of MeHgCl and HgCl2 with terminal acetylene R–CCH. The structures of the title compounds were characterized by NMR and IR spectroscopy, FAB mass spectrometry, X-ray crystallography and luminescence spectra. A new protocol for derivatization of inorganic and organic mercury(II) ions to mono- and dialkynyl mercury(II) compounds followed by extraction into dichloromethane is suggested, which can be effectively analyzed by HPLC technique using UV detection. The proposed procedure can offer a new opportunity for the simultaneous determination of inorganic Hg(II) and MeHg(II) in aqueous solutions.
The synthesis, structure and photophysical properties of some luminescent derivatives of inorganic mercury and methylmercury incorporating 4,4′-di(tert-butyl)-5-ethynyl-2,2′-bithiazole entity were described. These metal complexes can be utilized in the development of a new procedure for derivatization of inorganic and organic mercury(II) to Hg(II) alkynyls for HPLC analysis.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 6, 1 March 2006, Pages 1092–1100