کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1328587 | 977599 | 2006 | 5 صفحه PDF | دانلود رایگان |
A simple route to ω-aminoalkyltriethoxysilanes with variable alkylene chain lengths, (EtO)3Si(CH2)nNH2 (n = 5, 11) is described. These silyl linkers have been used to prepare urea-based compounds with H-bonding and hydrophobic interactions which enable the self-assembly of the molecules. These molecular precursors are suitable for the obtention of nano-structured hybrid silicas.
ω-Aminoalkyltrialkoxysilanes with variable chain linkers is directly available via a simple route by the reaction of NaN3 with ω-bromoalkyltrialkoxysilanes followed by hydrogenation with palladium catalyst. The reaction of 5-aminopentyltriethoxysilane with 1,4-diisocyanatobenzene led to the corresponding 1,4-bisurea derivative which under acid catalysed hydrolysis led to a lamellar hybrid.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 6, 1 March 2006, Pages 1126–1130