کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1328593 | 977599 | 2006 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: RhCl3-catalyzed disulfide exchange reaction using water solvent in homogeneous and heterogeneous systems RhCl3-catalyzed disulfide exchange reaction using water solvent in homogeneous and heterogeneous systems](/preview/png/1328593.png)
RhCl3 catalyzed the alkylthio exchange reaction of hydrophilic disulfides in water under homogeneous conditions, and equilibrium was attained in several hours. The reaction was applied to the exchange of unprotected glutathione disulfide. The reaction of dimethyl disulfide and hydrophilic disulfides under heterogeneous conditions also proceeded effectively. The mechanism turned out to be dependent on the water solubility of the substrates: The reaction of bis(3-hydroxypropyl) disulfide took place in the dimethyl disulfide phase, whereas the reaction of bis(6-aminohexyl) disulfide dihydrochloride proceeded in the water phase.
RhCl3 catalyzed the alkylthio exchange reaction of hydrophilic disulfides in water under homogeneous conditions, and equilibrium was attained in several hours. The reaction of dimethyl disulfide and hydrophilic disulfides under heterogeneous conditions also proceeded effectively.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 6, 1 March 2006, Pages 1159–1168