کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1328604 | 977599 | 2006 | 8 صفحه PDF | دانلود رایگان |
Reactions of 1,4-dilithiobutadienes (from 1,4-diiodo-1,2,3,4-tetraethylbutadiene (1) and 2,2′-dibromobiphenyl (7) with t-BuLi) with Me3SiCl gave siloles (3 and 9a) as the major products. No evidence for a disilylated butadiene was obtained. Use of higher molecular weight chlorosilanes ((allyl)Me2SiCl, BnMe2SiCl, and PhMe2SiCl) with dibromide 7 gave dimethylsilole 9a and a silane (10a, 10b, or 10c) resulting from trapping of the organic group by the chlorosilane.
Reactions of 1,4-dilithiobutadienes (e.g., 8) with RMe2SiCl gave siloles (e.g., 9) as the major products, along with a silane (R2SiMe2) formed by the reaction of RLi with the chlorosilane. There was no evidence for the formation of a disilylated butadiene.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 6, 1 March 2006, Pages 1257–1264