کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1336074 | 979567 | 2011 | 5 صفحه PDF | دانلود رایگان |

Two new complexes [MnIII(HL)2(acac)] and [MnII(HL)2]n have been obtained by reacting manganese(III) acetylacetonate monohydrate or manganese(II) chloride monohydrate with 2-salicylichydrazono-1,3-dithiolane ligand (H2L). Both compounds have been fully characterized by spectroscopic methods and single crystal X-ray diffraction. In the solid state, the molecular packing are described and discussed in term of weak H-bonds and short contacts. The unprecedented bridging coordination mode of this ligand lead to the first 2-salicylichydrazono-1,3-dithiolane-bridged coordination polymer [MnII(HL)2]n. The EPR spectrum of this compound was obtained with g ≈ 2.07, corresponding to a manganese ion (+II) in octahedral high-spin coordination sphere. The MnII complex exhibit paramagnetic behavior corresponding to quasi-isolated metal centers.
Two new complexes with 2-salicylichydrazono-1,3-dithiolane ligand (H2L) have been obtained by reacting manganese (III) acetylacetonate monohydrate or manganese (II) chloride with 2-salicylichydrazono-1,3-dithiolane ligand. Both compounds have been fully characterized by spectroscopic methods and single crystal X-ray diffraction. The unprecedented bridging coordination mode of this ligand lead to the first 2-salicylichydrazono-1,3-dithiolane-bridged coordination polymer.Figure optionsDownload as PowerPoint slideHighlights
► Two new Mn+III complexes with 2-salicylichydrazono-1,3-dithiolane ligand obtained.
► Crystal structures of monomeric as well as polymeric species determined.
► Unprecedented bridging coordination mode for the 2-salicylichydrazono-1,3-dithiolane ligand.
Journal: Polyhedron - Volume 30, Issue 11, 21 June 2011, Pages 1774–1778