Microwave-promoted efficient conversion of acetophenones to 1,3,5-triarylbenzenes catalyzed by H3PW12O40 and nano-silica supported H3PW12O40 as reusable catalysts

H3PW12O40 and nano-silica supported H3PW12O40 were found to be efficient heterogeneous catalysts for the preparation of 1,3,5-triarylbenzenes via triple self condensation of acetophenones under microwave irradiation and solvent-free conditions. High yields, short reaction times, easy work-up, easy availability and handling, eco-friendly and reusability of the catalysts are the main aspects of the present method. The catalytic mechanism of 1,3,5-triarylbenzenes synthesis is also proposed.

H3PW12O40 and nano-silica supported H3PW12O40 were found to be efficient heterogeneous catalysts for the preparation of 1,3,5-triarylbenzenes via triple self condensation of acetophenones under microwave irradiation and solvent-free conditions. High yields, short reaction times, easy work-up, easy availability and handling, ecofriendly and reusability of the catalysts are the main aspects of the present method. The catalytic mechanism of 1,3,5-triarylbenzenes synthesis is also proposed.Figure optionsDownload as PowerPoint slideHighlights
► By supporting tungstophosphoric acid on nano-silica.
► A heterogeneous catalyst was prepared.
► This heterogeneous catalyst was used for synthesis of 1,3,5-triarylbenzenes.
► The catalyst was reusable.