کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1375523 1500650 2014 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Unrefined wood hydrolysates are viable reactants for the reproducible synthesis of highly swellable hydrogels
ترجمه فارسی عنوان
هیدرولیزات چوب بدون رطوبت، واکنش دهنده های واکنش پذیر برای سنتز قابل بازیافت هیدروژل های بسیار پررنگ هستند
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی


• A robust sequential synthetic pathway for renewable hydrogel production is developed.
• Crude wood hydrolysate biomass, rich in hemicellulose and lignin, was used as a reactant.
• Swelling ratios as high as Qeq = 270 were achieved.

A value-adding robust and sequential synthetic pathway was elaborated to produce hydrogel structures with ionic character from crude acetylated galactoglucomannan-rich wood hydrolysate (WH). The WH was first-step liquor originating from a sulphite cracking pulp process for dissolving pulp. The synthetically modified WH fractions were verified at each step by NMR and FTIR, and the hydrogels were characterized with respect to their swelling and mechanical properties. Altering the crosslinking chemistry and the content of ionic moieties resulted in hydrogels with various swelling ratios and mechanical properties. Renewable hydrogel formulations with swelling ratios as high as Qeq = 270 were achieved.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 108, 8 August 2014, Pages 281–290
نویسندگان
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