کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1383263 | 1500637 | 2015 | 11 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Bionanocomposite films based on plasticized PLA–PHB/cellulose nanocrystal blends Bionanocomposite films based on plasticized PLA–PHB/cellulose nanocrystal blends](/preview/png/1383263.png)
• Cellulose nanocrystals were successfully incorporated in plasticized PLA–PHB blend.
• PHB enhanced the PLA crystallinity increasing the oxygen barrier properties.
• ATBC favored cellulose nanocrystal dispersion during processing.
• Surface modified CNCs showed better interaction with PLA, PHB and ATBC.
• ATBC and CNCs positively affect the PLA–PHB blend crystallinity and strechtability.
Optically transparent plasticized poly(lactic acid) (PLA) based bionanocomposite films intended for food packaging were prepared by melt blending. Materials were plasticized with 15 wt% of acetyl(tributyl citrate) (ATBC) to improve the material processability and to obtain flexibile films. Poly(hydroxybutyrate) (PHB) was used to increase PLA crystallinity. The thermal stability of the PLA–PHB blends was improved by the addition of 5 wt% of cellulose nanocrystals (CNC) or modified cellulose nanocrystals (CNCs) synthesized from microcrystalline cellulose. The combination of ATBC and cellulose nanocrystals, mainly the better dispersed CNCs, improved the interaction between PLA and PHB. Thus, an improvement on the oxygen barrier and stretchability was achieved in PLA–PHB–CNCs–ATBC which also displayed somewhat UV light blocking effect. All bionanocomposite films presented appropriate disintegration in compost suggesting their possible applications as biodegradable packaging materials.
Journal: Carbohydrate Polymers - Volume 121, 5 May 2015, Pages 265–275