کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1384402 | 982402 | 2011 | 4 صفحه PDF | دانلود رایگان |
The stereoselectivity of a 2-azido-2-deoxygalactosyl (GalN3) donor is found to strongly depend on the nature of the acceptors in glycosylation reactions. The order of the acceptor, the stereochemistry, and the configuration of the monosaccharide all affect the stereochemistry outcome. More reactive acceptors are observed to favor β-products, while less reactive acceptors afford more α-products.
The stereoselectivity of a 2-azido-2-deoxygalactosyl (GalN3) donor is found to strongly depend on the nature of the acceptors in glycosylation reactions. The order of the acceptor, the stereochemistry, and the configuration of the monosaccharide all affect the stereochemistry outcome. More reactive acceptors are observed to favor β-products, while less reactive acceptors afford more α-products.Figure optionsDownload as PowerPoint slide
Journal: Carbohydrate Research - Volume 346, Issue 15, 8 November 2011, Pages 2380–2383