کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1385604 982452 2006 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of new amino sugar derivatives from keto-sugars of d-xylose
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis of new amino sugar derivatives from keto-sugars of d-xylose
چکیده انگلیسی

Several amino sugars and imino sugar derivatives were synthesized from keto-sugars of d-xylose through a series of reactions such as the Henry reaction, hydrogenation reactions, and nucleophilic addition reactions or substitution reactions. Thiazine derivative 15 was obtained by the reaction of the keto-sugar with NH2CSNH2. Higher carbon sugar 16 was accidentally prepared at room temperature from the keto-sugar in the presence of NH2CONH2. The structures of the compounds were confirmed by spectral analysis. The absolute configurations of all asymmetric carbon atoms of 6 and 8 were confirmed by X-ray crystallographic analysis.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Research - Volume 341, Issue 14, 16 October 2006, Pages 2312–2320
نویسندگان
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