کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1387791 | 1500849 | 2015 | 8 صفحه PDF | دانلود رایگان |
• Glycosyl halides react with tetrathiomolybdate to give glycosyl dichalcogenides.
• Protocol for the synthesis of mixed glycosyl disulfides/selenenylsulfides is reported.
• A trisaccharide and a glycosyl amino acid containing mixed disulfide are synthesized.
An easy and mild method has been developed for the synthesis of mixed glycosyl disulfides/selenenylsulfides from glycosyl halides and diaryl/dialkyl dichalcogenides in the presence of benzyltriethylammonium tetrathiomolybdate [(BnEt3N)2MoS4]. The salient feature of this method is the sulfur transfer from [BnEt3N]2MoS4 to form glycosyl disulfides which with excess tetrathiomolybdate further undergo exchange reaction with other dichalcogenides in a one-pot operation.
Figure optionsDownload as PowerPoint slide
Journal: Carbohydrate Research - Volume 402, 30 January 2015, Pages 200–207