کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1387921 982738 2011 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Evidence of benzilic rearrangement during the electrochemical oxidation of d-glucose to d-glucaric acid
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Evidence of benzilic rearrangement during the electrochemical oxidation of d-glucose to d-glucaric acid
چکیده انگلیسی

During the course of the 2,2,6,6-tetramethyl-1-piperidinyloxy free radical-catalyzed electrochemical oxidation of d-glucose to d-glucaric acid a new side-product was observed. This compound was isolated and identified as a tricarboxylic acid of unique structure, which was named maribersonic acid. Its structure was proven by different experiments coupled with several analytical methods, and its appearance during the electrochemical oxidation of d-glucose was rationalized through a thorough study.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Research - Volume 346, Issue 4, 1 March 2011, Pages 512–518
نویسندگان
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