کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1389283 | 982859 | 2013 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Concise synthesis of clarhamnoside, a novel glycosphingolipid isolated from the marine sponge Agela clathrodes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The first total synthesis of a novel α-galactoglycosphingolipid clarhamnoside has been achieved through a straightforward strategy. A thiogalactosyl donor with a benzylidene group at C-4 and C-6 and nonparticipating p-methoxybenzyl group at C-2 was successfully employed in the stereocontrolled syntheses of α-GalGSLs. The N-Phth-protected trifluoroacetimidate donor for terminal disaccharide was successfully applied in constructing the [GalNAcβ-(1→6)-Gal] glycosidic linkage.
Clarhamnoside, a novel spongal α-GalGSL identified from new specimens of Agela clathrodes, has been first synthesized through a straightforward strategy.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Research - Volume 342, Issue 14, 15 October 2007, Pages 2003–2013
Journal: Carbohydrate Research - Volume 342, Issue 14, 15 October 2007, Pages 2003–2013
نویسندگان
Ning Ding, Chunxia Li, Yunpeng Liu, Zaihong Zhang, Yingxia Li,