کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1390287 | 1500877 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Concise synthesis of flavocommelin, 7-O-methylapigenin 6-C-, 4′-O-bis-β-d-glucoside, a component of the blue supramolecular pigment from Commelina communis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
• Flavocommelin was synthesized via in 9 steps from phloroacetophenone bisether in 31% yield.
• Regioselective O-debenzylation followed by cyclization were achieved.
• Final O-deacetylation and O-glycosylation proceeded regio- and stereoselectively.
Flavocommelin, 7-O-methylapigenin 6-C-, 4′-O-bis-β-d-glucoside, was synthesized in 9 steps from the C-glycosylation of 6-O-benzy-4-O-methylphloroacetophenone via the introduction of a cinnamoyl residue by aldol condensation and the formation of a C-ring by regioselective and oxidative ring-closure to regio- and stereoselective O-glycosylation for an overall yield of 31%.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Research - Volume 374, 7 June 2013, Pages 8–13
Journal: Carbohydrate Research - Volume 374, 7 June 2013, Pages 8–13
نویسندگان
Kazufumi Misawa, Yoshiki Gunji, Shingo Sato,