کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1390466 | 983078 | 2011 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Characterization of the hidden glass transition of amorphous cyclomaltoheptaose Characterization of the hidden glass transition of amorphous cyclomaltoheptaose](/preview/png/1390466.png)
An amorphous solid of cyclomaltoheptaose (β-cyclodextrin, β-CD) was formed by milling its crystalline form using a high-energy planetary mill at room temperature. The glass transition of this amorphous solid was found to occur above the thermal degradation point of the material preventing its direct observation and thus its full characterization. The corresponding glass transition temperature (Tg) and the ΔCp at Tg have, however, been estimated by extrapolation of Tg and ΔCp of closely related amorphous compounds. These compounds include methylated β-CD with different degrees of substitution and molecular alloys obtained by co-milling β-CD and methylated β-CD (DS 1.8) at different ratios. The physical characterization of the amorphous states have been performed by powder X-ray diffraction and differential scanning calorimetry, while the chemical integrity of β-CD upon milling was checked by NMR spectroscopy and mass spectrometry.
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Journal: Carbohydrate Research - Volume 346, Issue 14, 18 October 2011, Pages 2193–2199