کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1390598 | 983107 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Self-assembly of 6-O- and 6â²-O-hexadecylsucroses mixture under aqueous conditions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this paper, we report the self-assembly of 6-O- and 6â²-O-hexadecylsucroses mixture under aqueous conditions. The mixture was synthesized by a five-step sequence from sucrose. The SEM image of a sample prepared by drying a dispersion of the mixture in water showed nanoparticles with the diameter of â¼50Â nm and aggregates that were formed by further assembly of them. The XRD measurement of the sample exhibited the diffraction pattern assignable to face-centered cubic (FCC) structure and the diameter of a sphere, which took part in the FCC structure, was calculated to be 5.1Â nm. This value was relatively close to that observed in the DLS measurement of a dispersion of the mixture in water and estimated for a spherical micelle based on the molecular sizes of the two sucrose ethers. On the basis of the above findings, the following self-assembly process of the mixture under aqueous conditions was proposed. The mixture formed the spherical micelles with the diameter of â¼5-7Â nm in water. The micelles regularly organized according to the FCC structure during the drying process from the aqueous dispersion to construct the nanoparticles with the diameter of â¼50Â nm. Several numbers of the nanoparticles further assembled to form the aggregates.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Research - Volume 345, Issue 18, 10 December 2010, Pages 2718-2722
Journal: Carbohydrate Research - Volume 345, Issue 18, 10 December 2010, Pages 2718-2722
نویسندگان
Manami Kanemaru, Shin-ya Kuwahara, Kazuya Yamamoto, Yoshiro Kaneko, Jun-ichi Kadokawa,