کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1390782 983142 2007 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Borate esters of the methyl d-glucopyranosides
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Borate esters of the methyl d-glucopyranosides
چکیده انگلیسی

Methyl α- and β-d-glucopyranoside act as moderate chelators of a boron centre through their O-4/6 binding site whereas the trans/trans arrangement of the O-2/3/4 hydroxy functions is not suited to form a chelate with the small boron central atom. In this work we report the crystal structure of the bisdiolatoborate Na2[B(Me α-d-Glcp4,6H−2)(Me α-d-Glcp3,4,6H−3)]·NaOH·8H2O (1) along with a combined 11B and 13C NMR spectroscopic studies of borate–pyranoside solutions at different concentrations and pH. It is shown that crystallisation of a bisdiolatoborate needs both a high pH and a high total concentration.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Research - Volume 342, Issue 18, 28 December 2007, Pages 2801–2806
نویسندگان
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