کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1390926 983167 2006 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of α-d-Galf-(1→2)-d-galactitol and α-d-Galf-(1→2)[β-d-Galf-(1→3)]-d-galactitol, oligosaccharide derivatives from Bacteroides cellulosolvens glycoproteins
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis of α-d-Galf-(1→2)-d-galactitol and α-d-Galf-(1→2)[β-d-Galf-(1→3)]-d-galactitol, oligosaccharide derivatives from Bacteroides cellulosolvens glycoproteins
چکیده انگلیسی

The synthesis of α-d-galactofuranosyl-(1→2)-d-galactitol, which has been isolated by reductive β-elimination from glycoproteins of Bacteroides cellulosolvens and Clostridium thermocellum, is described. The approach of selective glycosylation of an aldono-1,4-lactone by the trichloroacetimidate method was employed. The synthesis of α-d-Galf-(1→2)[β-d-Galf-(1→3)]-d-Galol, that contains Galf units in both anomeric configurations, is also reported. These are the first synthetic oligosaccharides with α-d-Galf, previously found in natural products.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Research - Volume 341, Issue 15, 6 November 2006, Pages 2487–2497
نویسندگان
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