کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1413160 | 1508840 | 2016 | 9 صفحه PDF | دانلود رایگان |
Hierarchically structured carbon nanofiber/graphene/MnO2(CGMn) hybrid with oxygen and nitrogen functionalities was fabricated in the form of a web via electrospinning as an electrode material for supercapacitors. The CGMn electrode exhibited a high capacitance (225 Fg−1 at 1 mAcm−2), enhanced energy and power efficiency (15.8–13.6 Whkg−1 in the power density range of 197–4000 Wkg−1), and excellent capacitance retention (13% of the initial value at a discharge current of 20 mAcm−2) in a 6 M KOH aqueous electrolyte, because of the combination of the double-layer capacitance and the pseudocapacitive character associated with the surface redox-type reactions. The porosity and the number of heteroatoms of the CGMn composite were adjusted by changing the PMMA concentration and carbonization temperature. Therefore, the oxygen- and nitrogen-containing hierarchical porous CGMn hybrid prepared by a simple method is a promising candidate as an electrode material for supercapacitors.
Journal: Carbon - Volume 107, October 2016, Pages 783–791