کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1413357 | 1508858 | 2015 | 12 صفحه PDF | دانلود رایگان |
Low efficiency of oxygen reduction reaction (ORR) across cathode interfaces constitutes an obstacle to the bioelectricity generation in microbial fuel cells (MFCs). Advances in the property of carbon-based catalysts for ORR will have far-reaching implications for MFCs. Melamine is used as both carbon and nitrogen sources for preparing nitrogen-doped Fe-species/partly-graphitized carbon (Fe-species/NPGC) catalysts at relatively low temperature (640–700 °C). Main crystalline phases in Fe-species/NPGC-x (x = 640, 650, 660 and 700) change from iron carbide (Fe3C) to α-Fe as temperature increases. The OCO groups and structurally-bonded nitrogen (Fe-bonded N, pyridinic N and pyrrolic N) in PGC skeleton are favorable for improving electrical conductivity and catalytic activity. Single chamber MFCs with Fe/Fe3C/NPGC-650 generate power density of 1323 mW m−2, which is higher than those of Fe-species/NPGC-x (x = 640, 660 and 700) and Pt/C (1191 mW m−2). Minimum power density decline (1.75%) is achieved by Fe/NPGC-660, which is far lower than that (17.11%) of Pt/C. The highest coulombic efficiency (30%) is obtained by Fe/Fe3C/NPGC-650 due to the sufficient active-sites (embedded Fe3C or FeN species) and easy charge transport across the triphase interfaces, which are conducive to “capture–consume” the electrons for catalyzing ORR.
Journal: Carbon - Volume 89, August 2015, Pages 8–19