کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1413397 | 1508858 | 2015 | 12 صفحه PDF | دانلود رایگان |
The effect of boron substituted carbon (BCx, x ∼ 3–5) coatings on the hydrogen adsorption properties of porous carbons was investigated via spectroscopic characterization and hydrogen adsorption measurements. Thin films of BCx were synthesized by reacting BCl3 and benzene in a chemical vapor and then depositing the product as a solid (CVD). The BCx deposits were collected on microporous carbon substrates and mesoporous silica aerogel. High-resolution solid-state boron NMR, 11B HR-NMR, detected boron atoms in a symmetric chemical environment with trigonal coplanar coordination. Results from analyses based on NMR, X-ray photoelectron spectroscopy (XPS), and d-spacings, calculated from electron diffraction and X-ray diffraction (XRD) patterns, indicated that 17 at.% boron was substitutionally incorporated into the carbon framework. Thus the material has an empirical formula of BC4.9. Hydrogen adsorption data were collected at 100 bar and 25 °C. The BCx coatings reduced the surface area of the porous substrates by 30–50%. However, at the same time, they increased the heat of adsorption and the adsorption capacities per unit area by as much as a factor of five. Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTs) revealed wagging energies at 1190 cm−1 attributable to hydrogen interactions with C–B–C bonds.
Journal: Carbon - Volume 89, August 2015, Pages 392–403