کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1415032 | 985923 | 2012 | 12 صفحه PDF | دانلود رایگان |
Two phosphoric acid activation procedures; Activation after Hydrothermal Impregnation (recently published) and Activation after Incipient Wetness Impregnation instead of conventional impregnation are analyzed in two natural bio-fiber precursors: banana pseudostem and coconut fiber matting. Both procedures are compared analyzing, in both precursors, the influence that variables such as H3PO4/precursor ratio, activation temperature and impregnation time have on the resulting activated carbons (ACs) properties. The work also pays special attention to the mesoporosity development and the application of these ACs to adsorb gasoline vapors.Both H3PO4 activation procedures develop activated carbons having suitable activation yields and porosity developments, giving the Activation after Incipient Wetness Impregnation method better results than the Activation after Hydrothermal Impregnation. Both natural bio-fibers are good precursors, rendering the coconut fiber matting better results than the banana pseudostem. The variables studied affect the porosity development, being precursor and H3PO4/precursor ratio the variables that most affect. By a suitable selection of these variables, activated carbons having high adsorption capacities (BET above 2500 m2 g−1 and micropore volume above 1.00 cm3 g−1) and well developed mesoporosity (reaching 1.41 cm3 g−1), can be prepared. Most of the samples prepared perform very well for adsorbing gasoline vapors, showing a linear relationship with their resulting volumes.
Journal: Carbon - Volume 50, Issue 9, August 2012, Pages 3158–3169