کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1418401 | 986001 | 2006 | 7 صفحه PDF | دانلود رایگان |
Carbonization of iminodiacetonitrile by phosphoric acid leads to a carbogenic material with graphite oxide-mimic properties. Specifically, the molecularly derived nitrogenous solid is layered with relatively small lateral dimensions, highly dispersible in water providing clear sols and exhibits an appreciable ion-exchange capacity. The material’s structure and morphology have been extensively characterized with a variety of techniques. Notably, the EPR study is indicative of long-range spin interactions within the layered framework, and therefore, of an ordered state. Indeed, magnetic measurements support this finding by revealing a ferromagnetic transition at 50 K and magnetic hysteresis at 10 K. Overall, the method presents an alternative synthesis towards molecularly derived graphite oxide-like materials with novel properties.
Journal: Carbon - Volume 44, Issue 10, August 2006, Pages 1906–1912