کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1419206 986031 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Sulfurization of carbon surface for vapor phase mercury removal – I: Effect of temperature and sulfurization protocol
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی (عمومی)
پیش نمایش صفحه اول مقاله
Sulfurization of carbon surface for vapor phase mercury removal – I: Effect of temperature and sulfurization protocol
چکیده انگلیسی

The uptake of hydrogen sulfide by carbon materials (ACFs and BPL) under dry and anoxic conditions was tested using a fixed bed reactor system to determine the effects of sorbent properties, temperature (200–800 °C) and sulfurization protocols on the sulfur content, sulfur stability, sulfur distribution, and to elucidate possible reaction mechanisms for the formation of sulfur species. Sorbents with higher surface areas showed higher uptake capacity, indicating that active sites for sulfur bonding are formed during the formation of the pore structure. The sulfur content and stability generally increased with the increase in temperature due to a shift in the reaction mechanism. The sulfurization process is associated with the decomposition of surface functionalities, which creates active sites for sulfur bonding. The presence of H2S during the cooling process increased the sulfur content by increasing the presence of less stable sulfur forms. Sulfurized sorbents produced at high temperatures have pore structure similar to that of the virgin carbons.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbon - Volume 44, Issue 14, November 2006, Pages 2990–2997
نویسندگان
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