کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1430071 | 987194 | 2008 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Strontium PVC-membrane sensor based on 2-[(2-mercaptophenylimino)methyl]phenol Strontium PVC-membrane sensor based on 2-[(2-mercaptophenylimino)methyl]phenol](/preview/png/1430071.png)
The 2-[(2-mercaptophenylimino)methyl]phenol (MPMP) was used as an excellent ionophore in the construction of a Sr2+ PVC-based membrane sensor. The best performance was obtained with a membrane composition of 30% poly(vinyl chloride), 62% nitrobenzen (NB), 5.5% MPMP and 2.5% sodium tetraphenyl borate (NaTBP). This sensor demonstrates a good selectivity and sensitivity towards the strontium ion for many cations, including alkali, alkaline earth, transition and heavy metal ions. The sensor revealed a great enhancement in selectivity coefficients for strontium ions in comparison with the previously reported strontium sensors. The proposed sensor exhibits a Nernstian behavior (with a slope of 29.6 ± 0.3 mV per decade) for the concentration range of (1.0 × 10− 6–1.0 × 10− 1 M) with a detection limit of 5.5 × 10− 7 M (48.2 ng/mL). It illustrates a relatively fast response time in the whole concentration range (< 10 s) and it can be used for at least 10 weeks in a pH range of 2.8–9.6. The developed sensor was successfully used as an indicator electrode in the Sr(II) titration with EDTA and the Sr2+ ion recovery from binary mixtures.
Journal: Materials Science and Engineering: C - Volume 28, Issue 1, 10 January 2008, Pages 157–163