کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1430241 | 987198 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Voltammetric determination of ethamsylate in bulk solution and pharmaceutical tablet by nano-material composite-film coated electrode
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
بیومتریال
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چکیده انگلیسی
A sensitive electrochemical method was described for voltammetric determination of ethamsylate at a glassy carbon electrode (GCE) coated with a nano-material thin film. In this work, a nanometer material, namely, multi-wall carbon nanotubes (MWCNT) was dispersed successfully into water in the presence of dihexadecyl hydrogen phosphate (DHP) and a MWCNT-DHP composite film was conveniently obtained on the GCE surface. The electrochemical behavior of ethamsylate at this modified electrode was investigated and a pair of reversible redox peak was observed. Compared with the electrochemical response of ethamsylate at the bare GCE, the separation of peak potential (ÎEp) of ethamsylate decreased obviously from 438 to 40 mV and the current density of redox peaks increased greatly. Based on this, differential pulse voltammetry (DPV) was employed to determine ethamsylate. Various experimental parameters such as pH value of the supporting electrolyte, the amount of modifier and so on were optimized. Under optimal conditions, a linear response of ethamsylate was obtained in the range from 1.0 Ã 10â 6 to 2.0 Ã 10â 5 mol/L, and the detection limit was 6.0 Ã 10â 7 mol/L. The proposed method was successfully applied to detect ethamsylate in pharmaceutical samples.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Science and Engineering: C - Volume 29, Issue 8, 15 October 2009, Pages 2442-2447
Journal: Materials Science and Engineering: C - Volume 29, Issue 8, 15 October 2009, Pages 2442-2447
نویسندگان
Yingliang Wei, Chen Shao, Jinbo Liu,