کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1440543 | 1509368 | 2015 | 6 صفحه PDF | دانلود رایگان |
• G–P–Mn hybrids are prepared via a facile oil–water interfacial polymerization method.
• A binary oxidant composed of KMnO4 and (NH4)2S2O8 was used for aniline oxidation.
• PANI was nanofibered and MnO2-doped due to interfacial synthesis and binary oxidant.
• The G–P–Mn hybrids exhibit enhanced specific capacitance and good cycling stability.
• It opens a new avenue in designing hybrids in supercapacitor using multiple oxidants.
Graphene–polyaniline–MnO2 (G–P–Mn) hybrids were synthesized via a facile approach that includes the reduction of graphene oxide (GO) to graphene (G) by aniline and then followed by oil–water interfacial polymerization of aniline to polyaniline (PANI) using a binary oxidant of KMnO4 and (NH4)2S2O8. PANI was orderly nanofibered and MnO2-doped due to interfacial polymerization and the use of binary oxidant. The hybrids conclude electrical double layer capacitance of G and pseudo capacitance of PANI and MnO2, showing enhanced specific capacitance of 800.1 F g−1 at 0.4 A g−1 with good cycling stability.
Figure optionsDownload as PowerPoint slide
Journal: Synthetic Metals - Volume 209, November 2015, Pages 555–560