کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1460317 | 989604 | 2015 | 8 صفحه PDF | دانلود رایگان |

The aim of the current work is to prepare a novel boron-incorporated TiO2 film (B-TiO2 film) through MAO process in order to take advantages of the MAO technique and benefits of boron (B). The physicochemical properties and the in vitro bioactivity of B-TiO2 film are investigated in comparison with those of the control group without B (TiO2 film). Compared with TiO2 film, B-TiO2 film does not show obvious differences on morphology, surface roughness and phase composition. However, B-TiO2 film is found to be more hydrophilic than TiO2 film as the water contact angle decreases significantly from 77±1.7° to 65±3.1°. In simulated body fluid (SBF), an enhanced apatite-forming ability of B-TiO2 film is noticed compared to TiO2 film, indicating that the incorporation of B can improve the bioactivity of MAO-fabricated film. A possible mechanism is proposed to explain the enhanced bioactivity of B-TiO2 film. B is presented in MAO-fabricated film in forms of B2O3 and Ca2B2O5·H2O. Ca2B2O5·H2O is able to partially hydrolise in SBF and transform to boranol (B-OH) groups. The enhanced bioactivity might be attributed to the B-OH groups formed on the surface of B-TiO2 film in SBF. Results of the study suggest that B-TiO2 film is of great promise to be applied as bioactive material for biomedical applications.
Journal: Ceramics International - Volume 41, Issue 3, Part B, April 2015, Pages 4452–4459