کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1460994 989614 2014 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structural analysis and catalytic activity of Fe3O4 nanoparticles prepared by a facile co-precipitation method in a rotating packed bed
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Structural analysis and catalytic activity of Fe3O4 nanoparticles prepared by a facile co-precipitation method in a rotating packed bed
چکیده انگلیسی

Fe3O4 nanoparticles were prepared via a facile co-precipitation method in a rotating packed bed (RPB) in a continuous mode. Exactly how the rotating speed, flow rates of the reactants and precipitant, and concentrations of the reactants and precipitant affect the size of Fe3O4 nanoparticles was also investigated. Experimental results indicate that a higher rotating speed and larger flow rates of the reactants and precipitant were associated with a smaller size of Fe3O4 nanoparticles. However, concentrations of the reactants and precipitant only slightly affected the size of Fe3O4 nanoparticles. Additionally, the structural characterization of as-prepared Fe3O4 nanoparticles with an average size of 5.1 nm was studied using SEM, TEM, FTIR, XPS, and SQUID. Importantly, Fe3O4 nanoparticles displayed superparamagnetic behavior at 25 °C with saturation magnetization of 50 emu/g. Moreover, the catalytic activity of Fe3O4 nanoparticles was evaluated by the degradation of dyes (Rhodamine B: RhB, and Methylene blue: MB) in the presence of H2O2. According to those results, Fe3O4 nanoparticles could activate H2O2 and, thus, had a degradation efficiency of 98% and 80% for RhB and MB, respectively, in 120 min.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 40, Issue 7, Part B, August 2014, Pages 10275–10282
نویسندگان
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