کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1461361 989618 2014 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Porous titania microspheres with uniform wall thickness and high photoactivity
ترجمه فارسی عنوان
میکروسکپ های تیتانا ظریف با ضخامت دیوار یکنواخت و عکسبرداری بالا
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
چکیده انگلیسی

Highly porous titania particles were prepared by depositing thin films of titania, using alternating reactions of TiCl4 and hydrogen peroxide, on poly(styrene-divinylbenzene) (PS-DVB) template particles via atomic layer deposition (ALD) at 77 °C. The composition of the titania films was verified by XPS analysis and the titania films were directly observed by TEM. TGA/DSC was used to study the thermal decomposition of the polymer template. Porous titania particles with uniform wall thicknesses were successfully obtained after the template PS-DVB was removed by oxidation in air at 400 °C for 24 h. Verification of the resulting porous structure of the titania particles was done by cross-sectional SEM and nitrogen adsorption–desorption analysis. Porous titania particles were treated at different temperatures. XRD analysis was used to determine the microstructure and phase transformation of titania at elevated temperatures. The photocatalytic activity of these porous titania particles was studied by methylene blue decomposition under UV light at room temperature and was found to be comparable to that of commercial anatase titania nanoparticles (~20 nm). Depositing Na2SO4 on TiO2 retarded the TiO2 phase transformation from anatase to rutile during calcination and, thus, greatly increased the photoactivity of the porous titania particles.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 40, Issue 2, March 2014, Pages 3097–3103
نویسندگان
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