کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1462452 989631 2012 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of calcium phosphate-based composite nanopowders by mechanochemical process and subsequent thermal treatment
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Synthesis of calcium phosphate-based composite nanopowders by mechanochemical process and subsequent thermal treatment
چکیده انگلیسی

One-step mechanochemical process followed by thermal treatment has been used to produce calcium phosphate-based composite nanopowders. Effects of milling and subsequent heat treatment on the phase transition as well as structural features were investigated. The products were characterized by powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM) techniques. The results revealed that the dominant phases after mechanical activation were hydroxyapatite, anatase (TiO2), and periclase (MgO), while after thermal annealing process at 700 °C hydroxyapatite along with geikielite (MgTiO3) and periclase (MgO) were the major phases. In addition, decomposition of hydroxyapatite to tricalcium phosphate (β-TCP) occurred after heat treatment in the range 900–1100 °C which resulted in the formation of tricalcium phosphate-based composite nanopowders. Evaluation of structural features of the samples calculated by X-ray diffraction profiles analysis indicated that the average crystallite size of hydroxyapatite after 10 h of milling and subsequent heat treatment at 700 °C were about 21 and 34 nm, respectively. TEM and SEM studies exhibited that the considerable morphological changes at temperatures ≥900 °C had to be ascribed not only to grain growth, but also for the transformation of hydroxyapatite to β-TCP.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 38, Issue 8, December 2012, Pages 6729–6738
نویسندگان
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