کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
147290 | 456388 | 2014 | 9 صفحه PDF | دانلود رایگان |
• Heteropolyanion-based mesoporous sulfonated copolymer catalyst is prepared.
• The catalyst is highly active in F–C reaction of arenes with benzyl alcohol.
• The catalyst is heterogeneous with high potential for reusability.
• Mesopores and heteropolyanion play key roles in catalytic performance.
A new heteropolyanion-based acidic ionic liquid-functionalized mesoporous copolymer P(VB-VMS)PW was prepared by anion-exchange of 1,3-propanesulfonate poly(N-vinylimidazole-co-divinylbenzene) with Keggin 12-phosphotungstic acid. The obtained hybrid material was characterized by fourier transform infrared spectroscopy, thermogravimetry, nuclear magnetic resonance, scanning electron microscope, X-ray diffractometer, nitrogen sorption isotherm, elemental analysis and Hammett indicator. Its catalytic performance was assessed and compared with analogues in the Friedel–Crafts benzylation reaction between single-ring aromatic compounds with benzyl alcohol under solvent-free condition. Owning to the suitable mesoporous copolymeric structure, P(VB-VMS)PW showed a relatively high yield of benzylating products (96.7%), and it could be facilely recovered and reused. Besides, functionalization of the mesoporous ionic copolymer with heteropolyanion was able to enhance the structural stability and the acidity of the sulfonic group, favoring superior acid catalysis performance in benzylation reaction.
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Journal: Chemical Engineering Journal - Volume 254, 15 October 2014, Pages 54–62