کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1478851 1510150 2006 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Deposition of calcium phosphate coatings with defined chemical properties using the electrostatic spray deposition technique
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Deposition of calcium phosphate coatings with defined chemical properties using the electrostatic spray deposition technique
چکیده انگلیسی
The results showed that the chemical properties of the coatings were determined by both physical, apparatus-related factors and chemical, solution-related parameters. By varying the processing parameters of the technique, several crystal phases and phase mixtures were obtained, ranging from carbonate-free phases such as meta- and pyrophosphates, monetite and various tricalcium phosphates to carbonate-containing phases such as various carbonate apatites and calcite. On the basis of these results, a chemical mechanism of coating formation was proposed. Essentially, the deposition of the various crystal phases was the result of an acid-base reaction between basic CO32− groups (originating from solvent decomposition reactions) and acidic HPO42− groups from an intermediate monetite (CaHPO4) phase of the CaP precipitate. The amount of carbonate incorporation (ranging from 0 to 15 wt%) determined the crystal and molecular structure of the deposited coatings.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 26, Issues 4–5, 2006, Pages 487-493
نویسندگان
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