کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
148323 456409 2014 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Surfactant assisted nano-composite cation exchanger: Development, characterization and applications for the removal of toxic Pb2+ from aqueous medium
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Surfactant assisted nano-composite cation exchanger: Development, characterization and applications for the removal of toxic Pb2+ from aqueous medium
چکیده انگلیسی


• Synthesis of a new nano-composite cation exchange material (SDS-AZS).
• SDS-AZS was effectively used for removal of important environmental pollutant (Pb2+).
• Uptake rate of Pb2+ was fast and equilibrium established within 40 min.
• Equilibrium time was independent of initial concentration of Pb2+.
• Practical efficiency of the SDS-AZS was explored in real water sample.

A novel nano-composite cation exchanger sodium dodecyl sulfate acrylamide Zr(IV) selenite (SDS-AZS) was developed by sol–gel method. The physico-chemical properties of SDS-AZS were studied using FTIR, TGA, XRD, SEM, EDX, TEM and elemental analyses. The material was effectively used for the removal of Pb2+ which is an important environmental pollutant. Batch experiments were performed as a function of various experimental parameters such as effect of pH (2–10), contact time (5–60 min), SDS-AZS dose (0.1–1.0 g), initial Pb2+ concentration (10–30 μg mL−1) and temperature (25–55 °C). The uptake rate of Pb2+ onto SDS-AZS was rapid and equilibrium established within 40 min. Kinetic studies showed better applicability for pseudo-first-order model. The applicability of Langmuir, Freundlich and Temkin isotherm models was investigated and the Freundlich isotherm exhibited the best fit with the experimental data. The values of thermodynamic parameters (ΔG°, ΔH° and ΔS°) were computed from the Van’t Hoff plot which showed that the adsorption of Pb2+ was feasible, endothermic and spontaneous. The regeneration studies were carried out which demonstrated a decrease in the recovery of Pb2+ from 90% to 79% after four consecutive cycles. On the basis of good uptake capacity, SDS-AZS was successfully used for the removal and recovery Pb2+ from a real water sample spiked with Pb2+.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 235, 1 January 2014, Pages 100–108
نویسندگان
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