کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1485580 | 991665 | 2007 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and physico-chemical characterization of metal free, sodium and potassium phthalocyanine complexes Synthesis and physico-chemical characterization of metal free, sodium and potassium phthalocyanine complexes](/preview/png/1485580.png)
Sodium phthalocyanine (Na2Pc), potassium phthalocyanine (K2Pc) and hydrogen phthalocyanine (H2Pc) are synthesized in pure state. These complexes are characterized using physico-chemical methods like electronic, IR spectral, magnetic susceptibility measurements, thermogravimetric analysis and X-ray powder diffraction studies. Kinetic and thermodynamic parameters associated with the thermal decomposition were calculated using thermogravimetric analytical data. X-ray diffraction studies revealed that these complexes are having monoclinic crystal lattice structure. Electrical conductivity studies are carried out using two-probe technique in the temperature range 298–473 K for each complex. Sodium phthalocyanine showed semiconducting behavior, whereas potassium phthalocyanine showed first metallic behavior in the temperature range 300–378 K and then semiconducting property in the temperature range 383–473 K. But hydrogen phthalocyanine showed semiconducting behavior in the temperature range 300–390 K and metallic conduction behavior in the temperature range 395–473 K.
Journal: Journal of Non-Crystalline Solids - Volume 353, Issue 4, 15 March 2007, Pages 384–389