کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
148639 456420 2013 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solid phase extraction of Pb(II), Cu(II), Cd(II) and Cr(III) with syringe technique using novel silica-supported bis(diazoimine) ligands
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Solid phase extraction of Pb(II), Cu(II), Cd(II) and Cr(III) with syringe technique using novel silica-supported bis(diazoimine) ligands
چکیده انگلیسی

Novel multidentate silica-supported bis(diazoimine) ligands were synthesized and characterized by elemental analysis, solid phase NMR (29Si and 13C CP MAS), FT-IR, TG/DTA, SEM and EDX techniques. In the synthesis, diazotized electrophiles of 1,4-diaminobenzene and 1,3-diaminobenzene coupled with 2,4-dihydroxybenzaldehyde to give bis(diazocarbonyl) compounds; (A1: 5,5′-(1,4-phenylenebis(diazene-2,1-diyl))bis(2,4-dihydroxybenzaldehyde and A2: 5,5′-1,3-phenylenebis(diazene-2,1-diyl))bis(2,4-dihydroxybenzaldehyde)) which were chemically supported with amino-modified silica-gel (L1 and L2). The electrochemical properties of bis(diazocarbonyl) compounds (A1 and A2) were investigated by cyclic voltammetry. Optimum solid phase extraction parameters of the synthesized sorbents for syringe and batch techniques were determined by using ICP-OES. At optimum conditions, the recoveries of Pb(II), Cu(II), Cd(II) and Cr(III) were 95–99% ± 2–3%. All the multifunctional multidentate silica-supported ligands showed highly effective solid phase extraction properties.

Figure optionsDownload as PowerPoint slideHighlights
► Synthesis of novel bis(diazoaldehyde)s and silica-supported bis(diazoimine) ligands.
► Characterization and electrochemical properties of the novel compounds.
► Multidentate bis(diazoimine) ligands exhibit highly efficient solid phase extraction properties.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 220, 15 March 2013, Pages 420–430
نویسندگان
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