Synthesis and characterization of samarium-doped ZnS nanoparticles: A novel visible light responsive photocatalyst

• Sm-doped ZnS Nanomaterials were synthesized by hydrothermal method.
• The as-prepared compounds were characterized by XRD, TEM, XPS, SEM and UV techniques.
• The photocatalytic effect of compounds was determined by Reactive Red 43 degradation.
• The degradation of RRed 43 followed the Langmuir–Hinshelwood kinetic model.

We prepared pure and samarium-doped ZnS (SmxZn1−xS1+0.5x) nanoparticles via hydrothermal process at 160 °C for 24 h. XRD analysis shows that the particles were well crystallized and corresponds to a cubic sphalerite phase. SEM and TEM images indicate that the sizes of the particles were in the range of 20–60 nm. The photocatalytic activity of Sm-doped ZnS nanoparticles was evaluated by monitoring the decolorization of Reactive Red 43 in aqueous solution under visible light irradiation. The color removal efficiency of Sm0.04Zn0.96S and pure ZnS was 95.1% and 28.7% after 120 min of treatment, respectively. Among the different amounts of dopant agent used, 4% Sm-doped ZnS nanoparticles indicated the highest decolorization. We found that the presence of inorganic ions such as Cl−, CO32− and other radical scavengers such as buthanol and isopropyl alcohol reduced the decolorization efficiency.

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