Rare earth doped LiYbF4 phosphors with controlled morphologies: Hydrothermal synthesis and luminescent properties

High quality monodisperse LiYbF4 microparticles with shape of octahedron had been prepared via a facile hydrothermal route. The crystalline phase, size, morphology and luminescence properties were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence (PL) spectra and Commission Internationale de L’Eclairage (CIE 1931) chromaticity coordinates, respectively. The influences of reaction temperature, reaction time and the molar ratio of EDTA to Yb3+ on the crystal phases and shapes of as-prepared products had been investigated in detail. The upconversion (UC) luminescence properties of LiYb1−xF4:xEr3+ (x =0.1, 0.2, 0.5, 1, 2, 5 and 10 mol%) particles with octahedral microstructures were studied under 976 nm excitation. The results showed that the luminescence colors of the corresponding products could be tuned to bright green by changing the doping concentration of Er3+ ion. The luminescence mechanisms for the doped Er3+ ion were thoroughly analyzed, showing great potential in applications such as biolabels, displays and other optical technologies.

Figure optionsDownload as PowerPoint slideHighlights
► LiYbF4 microparticles as an excellent upconverting materials.
► High temperature and long time can favor high crystalline LiYbF4 microparticles.
► The shape of LiYbF4 microparticles can be tuned by the molar ratio of EDTA to Yb3+.
► Bright green emission can be obtained by changing the doping concentration of Er3+.