کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
149244 | 456429 | 2012 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: An efficient method for preparation of propyl gallate using Brønsted acidic ionic liquid N-methyl pyrrolidonium hydrosulfate [Hnmp]HSO4 An efficient method for preparation of propyl gallate using Brønsted acidic ionic liquid N-methyl pyrrolidonium hydrosulfate [Hnmp]HSO4](/preview/png/149244.png)
The synthesis of propyl gallate using Brønsted acidic ionic liquid N-methyl pyrrolidonium hydrosulfate [Hnmp]HSO4 as an efficient catalyst with gallic acid and n-propanol as materials was studied. The influence factors, such as the selection of water-carrying agent, reaction temperature, molar ratio of reactants, the dosage of catalyst, and the reaction time were also investigated. The results showed the optimum reaction conditions were as follows: the molar ratio of n-propanol and gallic acid and catalyst was 5:1:0.3, reaction time was 5 h and the yield of propyl gallate was up to 89.8% without water-carrying agent at 95–105 °C.
► Green synthesis of propyl gallate with an environmentally friendly catalyst without poisonous water-carrying agent.
► The mechanism for the synthesis using [Hnmp]HSO4 as catalyst.
► Influence of the reaction conditions on the synthesis of propyl gallate.
Journal: Chemical Engineering Journal - Volume 209, 15 October 2012, Pages 464–468