کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
149665 456435 2012 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Peptization technique in the synthesis of titania–silica composites and their photocatalytic properties
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Peptization technique in the synthesis of titania–silica composites and their photocatalytic properties
چکیده انگلیسی

A comparative study of titania–silica composite (TSC) synthesized via peptization sol–gel method was conducted. Typically, titanium hydroxide gel (Ti(OH)4) was formed by condensation of titanium oxychloride solution using adequate amount of ammonium hydroxide solution. The preformed gel was peptized either in silicic acid (SA) or nitric acid (NA) to form a sol. The composite was characterized by XRD, FTIR, SEM, TEM, TGA, and N2 physisorption studies. The XRD patterns and the TEM micrographs confirmed that thermal-derived samples of the composite, formed using silicic acid as a silica source and peptizing agent (TSC–SA), yielded TiO2SiO2 composite with a single-phase (anatase phase); while a mixture of both anatase and rutile phases were observed in the composite (TSC–NA), where nitric acid was used as a peptizing agent. FTIR analysis showed the vibration band assignable to the TiOSi bond at 945 cm−1, suggesting that titania was incorporated into silica to form a composite. Furthermore, a simple experiment of photodegradation of methyl orange in the presence of sunlight was performed to demonstrate the practical efficacy of the composites synthesized via this method. The results indicated that the calcined samples of TSC–NA-800 had the highest activity due to its superior properties.

Figure optionsDownload as PowerPoint slideHighlights
► Titania–silica composites are prepared via peptization sol–gel method.
► Silicic acid yielded from water glass is used as a precursor and peptizing agent.
► The composite formed by peptizing Ti(OH)4 gel into silicic acid has anatase phase.
► Anatase and rutile form in the composite where nitric acid was a peptizing agent.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volumes 198–199, 1 August 2012, Pages 122–129
نویسندگان
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