کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1506372 993792 2010 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A 2-D metal-organic framework of the iron-based 18-metallacrown-6 with N-(methyl-maleamic ester) terminal ligand
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
A 2-D metal-organic framework of the iron-based 18-metallacrown-6 with N-(methyl-maleamic ester) terminal ligand
چکیده انگلیسی

An 18-membered complex, [Fe(MMSHZ)(DMF)]6 (1) [MMSHZ = N-(methyl-maleamic ester)acylsalicylhydrazine] was synthesized and structurally characterized. There are not only particular geometry configurations of N-terminal groups which result in the unique shape of the centric cavity, but also inter- and intra-molecular interactions assembling adjacent molecules into 2-D framework in complex 1. Temperature-dependent magnetic susceptibility measurements indicate that this complex exhibits significantly antiferromagnetic coupling among the metal centers.

An 18-membered complex, [Fe(MMSHZ)(DMF)]6 (1) [MMSHZ = N-(methyl-maleamic ester)acylsalicylhydrazine] was reported. The complex 1 exhibits not only unique coordination configurations of N-terminal groups resulting in the particular shape of the cavity in complex 1, but also inter- and intra-molecular interactions assembling this complex into the first 2-D framework via intermolecular EF stacking interactions and C–H⋯O hydrogen-bond interactions.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Sciences - Volume 12, Issue 4, April 2010, Pages 461–465
نویسندگان
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