کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
150657 | 456454 | 2011 | 7 صفحه PDF | دانلود رایگان |
In the present work, novel catalysts-Pd nanoparticles loaded on glass beads with an egg–shell structure were prepared through the combination of the subcritical water treatment process and the ion-exchange method. SEM and TEM images showed that the Pd nanoparticles loaded on the shell with depth of approximately 3–4 μm were highly monodispersed with an average diameter of 4 nm. The conversion of enthylanthraquinone as much as 60% was realized in less than 2 s, besides, the space–time yield of the hydrogenation of ethylanthraquinone reached as high as 3800 gH2O2/gpd/h3800 gH2O2/gpd/h, and the hydrogenation efficiency was 11.2 gH2O2/Lworking soluiton11.2 gH2O2/Lworking soluiton with the novel catalyst.
Novel catalyst-Pd nanoparticles loaded on glass beads with a core–shell structure were prepared through the combination of the subcritical water treatment process and the ion-exchange method. The prepared catalysts were packed in a tubular reactor and they showed better performance in the hydrogenation of 2-ethylanthraquinone compared with those of the commercial production or of the works in relevant literature.Figure optionsDownload as PowerPoint slideHighlights
► Novel catalyst-Pd nanoparticles loaded on glass beads with an egg–shell structure were prepared.
► The conversion of enthylanthraquinone as much as 60% was realized in less than 2 s.
► The space–time yield reached as high as 3800 gH2O2/gpd/h3800 gH2O2/gpd/h.
► The hydrogenation efficiency reached 11.2 gH2O2/Lworking soluiton11.2 gH2O2/Lworking soluiton.
Journal: Chemical Engineering Journal - Volume 173, Issue 1, 1 September 2011, Pages 226–232