کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
150666 456455 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Kinetics study of the perchloroethylene hydrofluorination into pentafluoroethane (Freon 125) over chromium-based catalyst
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Kinetics study of the perchloroethylene hydrofluorination into pentafluoroethane (Freon 125) over chromium-based catalyst
چکیده انگلیسی

The gas-phase hydrofluorination of perchloroethylene (PCE) into pentafluoroethane (non ozone-depleting Freon 125) at T = 330–390 °C and P = 0.4 MPa in the presence of a chromium–magnesium catalyst has been studied. A hydrofluorination scheme including main product and by-products formation routes is deduced from the observed dependences of particular products selectivity. The kinetic model of the PCE hydrofluorination has been developed. The rate parameters and the activation energy of the reactions were determined. The model satisfactorily describes the experimental data in the temperature range 330–390 °C.


► We study the gas-phase hydrofluorination of perchloroethylene into pentafluoroethane (non ozone- depleting Freon 125) in the presence of a chromium–magnesium catalyst.
► In this study we suggest the hydrofluorination scheme including main product and by-products formation routes.
► The kinetic model of the reaction was developed and its kinetic parameters was determined.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volumes 176–177, 1 December 2011, Pages 22–25
نویسندگان
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