کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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151339 | 456470 | 2011 | 6 صفحه PDF | دانلود رایگان |
Zn–Ti layered double hydroxides (LDHs) with different Zn/Ti ratio have been synthesized by co-precipitation of zinc and titanium salts from homogeneous solution, which were demonstrated as efficient visible-light photocatalysts. Powder X-ray diffraction (PXRD), scanning electron microscope (SEM), high-resolution transmission electron microscopy (HRTEM) and Brunauer–Emmett–Teller (BET) revealed that the resulting Zn–Ti LDHs possess high crystallinity, hierarchical structure as well as large specific surface area (91.96–107.9 m2 g−1). UV–vis diffuse reflection spectroscopy (DRS) confirmed that Zn–Ti LDHs show a broad absorption in visible light region (400–700 nm). With a low band gap of ∼3.06 eV, the as-prepared Zn–Ti LDHs displayed significant photocatalytic activity for the degradation of methylene blue (MB) under visible-light irradiation (∼100% of degradation percentage in 100 min), which is much higher than that of commercial product (Degussa P25). Therefore, this work provides a detailed understanding of semiconductor properties of Zn–Ti LDHs which was unrevealed previously, and demonstrates its potential application in the field of photocatalysis.
Journal: Chemical Engineering Journal - Volume 168, Issue 2, 1 April 2011, Pages 519–524