کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
151549 | 456473 | 2010 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The oxidation of styrene by chromium–silica heterogeneous catalyst prepared from rice husk
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The oxidation of styrene by chromium–silica heterogeneous catalyst prepared from rice husk The oxidation of styrene by chromium–silica heterogeneous catalyst prepared from rice husk](/preview/png/151549.png)
چکیده انگلیسی
Chromium was incorporated into the silica matrix extracted from rice husk in basic, neutral and acidic medium. The prepared catalysts were labeled as RHCr-10, RHCr-7 and RHCr-3 according to their pH. The specific surface area of RHCr-10, RHCr-7 and RHCr-3 was determined to be 144, 143 and 564 m2 g−1, respectively. The XRD results showed the catalysts to be amorphous. RHCr-3 showed better catalytic activity with 99.92% conversion of styrene. Benzaldehyde was the major product with styrene oxide, phenyl acetaldehyde, acetophenone, 1-phenylethanol, phenylglyoxal, styrene glycol and benzoic acid as by-products. Leaching of chromium was minimal and RHCr-3 could be recycled several times.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 160, Issue 2, 1 June 2010, Pages 742–750
Journal: Chemical Engineering Journal - Volume 160, Issue 2, 1 June 2010, Pages 742–750
نویسندگان
Farook Adam, Anwar Iqbal,