کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
152276 | 456492 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Highly selective oxidation of benzyl alcohol to benzaldehyde with hydrogen peroxide by biphasic catalysis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Highly selective oxidation of benzyl alcohol to benzaldehyde with hydrogen peroxide by biphasic catalysis Highly selective oxidation of benzyl alcohol to benzaldehyde with hydrogen peroxide by biphasic catalysis](/preview/png/152276.png)
چکیده انگلیسی
An environmentally benign oxidation of benzyl alcohol to benzaldehyde with hydrogen peroxide as oxidant and metal dodecanesulfonate salts as catalysts was conducted under solvent-free condition by biphasic catalysis. Ferric tridodecanesulfonate showed excellent catalytic activity exhibiting complete conversion of benzyl alcohol with 194.4 mol/molcat turnover number (TON) and nearly 100% selectivity to benzaldehyde at ambient pressure and 90 °C. This catalyst can be recovered and reused for three times without a significant loss in its activity and selectivity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 162, Issue 2, 15 August 2010, Pages 738–742
Journal: Chemical Engineering Journal - Volume 162, Issue 2, 15 August 2010, Pages 738–742
نویسندگان
Yuanyuan Yu, Bin Lu, Xiaoguang Wang, Jingxiang Zhao, Xuanzhang Wang, Qinghai Cai,