Effect of millimeter-wave irradiation on cation interdiffusion in the calcium titanate/strontium titanate ceramic couple

► Interdiffusion was enhanced by MMW (millimeter-wave) irradiation. ► At the same time the apparent activation energy decreased. ► The enhancement degrees were different between the transport species. ► The observed diffusion enhancement can be ascribed to a nonthermal effect. ► MMW irradiation could be an effective means of preparing novel complex oxides.