Fabrication of Er3+/Yb3+ co-doped Y2O3 transparent ceramics by solid-state reaction method and its up-conversion luminescence

Highly transparent Er3+/Yb3+ co-doped yttria ceramics were fabricated by a solid-state reaction method using high purity Y2O3, Er2O3 and Yb2O3 powders as starting materials and La2O3 as an additive. The microstructure evolution and optical properties of the ceramics were investigated. Fully dense Y2O3: Er3+, Yb3+ ceramics with mean grain size of about 60 μm were obtained by vacuum sintering at 1800 °C for 10 h. The highest transmittance of the ceramic sample is more than 75% in the range from 500 to 3000 nm. Under the 980 nm laser diode excitation, the ceramic sample exhibits intense up-conversion luminescence, which is centered at 561 and 662 nm respectively.

► High-purity Y2O3 powder as starting materials and La2O3 as additive.
► Solid-state reaction fabrication of Er3+/Yb3+ co-doped yttria transparent ceramics.
► Vacuum sintering at high temperature enables the densification of the ceramics.
► The ceramics exhibit high transmittance and intense up-conversion luminescence.